浙江大學(xué)高分子科學(xué)與工程學(xué)系副教授，博士，博士生導(dǎo)師。近年來作為項(xiàng)目負(fù)責(zé)人主持國家自然科學(xué)基金項(xiàng)目4項(xiàng);浙江省杰出青年基金項(xiàng)目1項(xiàng);中國博士后自然科學(xué)基金一等資助項(xiàng)目1項(xiàng);浙江省自然科學(xué)基金項(xiàng)目1項(xiàng);浙江省科技廳社會(huì)公益技術(shù)項(xiàng)目1項(xiàng);承擔(dān)香港建滔化工集團(tuán)、德國巴斯夫委托的國內(nèi)外研究課題4項(xiàng)。在Chemical Science, Macromolecules, Polymer Chemistry, Macromolecular Rapid Communications, Journal of polymer science Part A: Polymer Chemistry, Polymer 等國內(nèi)外期刊發(fā)表 SCI論文50余篇，授權(quán)中國發(fā)明專利20項(xiàng)，授權(quán)美國專利1項(xiàng)。

　　主持/參與科研項(xiàng)目

　　主持的國家級(jí)項(xiàng)目：

　　1、一釜合成多嵌段CO2基共聚物及其結(jié)構(gòu)與性能、國家自然科學(xué)基金面上項(xiàng)目、2015/01-2018/12。

　　2、氧硫化碳-環(huán)氧化物可控催化共聚及機(jī)理研究、國家自然科學(xué)基金面上項(xiàng)目、2013/01-2016/12。

　　3、基于CO2/環(huán)氧化物可控共聚技術(shù)合成可降解的聚合物分子刷、國家自然科學(xué)基金面上項(xiàng)目、2011/01-2013/12。

　　專利、論文及著作

　　代表性專利：

　　1. Metal cyanide complex catalyst, preparation method and uses thereof，美國發(fā)明專利，授權(quán)，US13394267，2014.10, 1/5。

　　2. 一種鏈結(jié)構(gòu)規(guī)整的聚單硫代碳酸酯的制備方法 ，發(fā)明專利，授權(quán)，201310202810.0, 2015.05，1/4。

　　3. 一種用于碳酸二甲酯合成的催化劑的制備方法及應(yīng)用，發(fā)明專利，授權(quán)，201210148342.9，2014.04，1/4。

　　4. 一種納米結(jié)構(gòu)環(huán)氧樹脂固化物的制備方法和用途，發(fā)明專利，授權(quán)，201010225029.1，2012.03，1/3。

　　5. 一種鏈結(jié)構(gòu)規(guī)整的脂肪族聚碳酸酯的合成方法，發(fā)明專利，授權(quán)， 201310035031.6，2015.02，1/3。

　　6. 一種雙組分雙金屬催化劑的合成方法及應(yīng)用，發(fā)明專利，授權(quán)， 201110428195.6，2015.04，1/4。

　　7. 含聚酯鏈節(jié)和聚碳酸酯鏈節(jié)的三元共聚物及其合成方法，發(fā)明專利，授權(quán)，200910098650.3，2011.05，1/3。

　　8. 主鏈和側(cè)鏈均為碳-氧雜鏈結(jié)構(gòu)的聚合物分子刷、合成方法，發(fā)明專利，授權(quán)， 201110249714.2，2013.08，1/5。

　　9. 金屬氰化物配位催化劑催化制備脂肪族聚碳酸酯的方法，發(fā)明專利，授權(quán)， 201010253928.2，2012.05，1/5。

　　10. 一種金屬氰化物配位催化劑及其制備方法和應(yīng)用，發(fā)明專利，授權(quán)，201010253936.7，2012.05，1/5。

　　論文：

　　2015

　　(1) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Well-defined high refractive index poly(monothiocarbonate) with tunable Abbe's numbers and glass-transition temperatures via terpolymerization. Polymer Chemistry 2015, 6, 4978-4983.

　　(2) Li, Y.; Hong, J.-L.; Wei, R.-J.; Zhang, Y.-Y.; Tong, Z.-Z.; Zhang, X.-H.*; Du, B.-Y.; Xu, J.-T.; Fan, Z.-Q. Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone. Chemical Science 2015, 6, 1530-1536.

　　(3) Zhang, Y.-Y.; Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Efficient solvent-free alternating copolymerization of CO2 with 1, 2-epoxydodecane and terpolymerization with styrene oxide via heterogeneous catalysis. Journal of Polymer Science Part A: Polymer Chemistry 2015, 53, 737-744.

　　(4) Zhang, Y.-Y.; Li, Y.; Zhou, X.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Synthesis of an Amphiphilic Brush Copolymer by a Highly Efficient “Grafting onto” Approach via CO2 Chemistry. Macromolecular Rapid Communications 2015, 36, 852-857.

　　(5) Zhang, X.-H.*; Wei, R.-J.; Zhang, Y.-Y.; Du, B.-Y.; Fan, Z.-Q. Carbon Dioxide/Epoxide Copolymerization via a Nanosized Zinc–Cobalt(III) Double Metal Cyanide Complex: Substituent Effects of Epoxides on Polycarbonate Selectivity, Regioselectivity and Glass Transition Temperatures. Macromolecules 2015, 48, 536-544.

　　(6) Min, Y.-Q.; Huang, S.-Y.; Wang, Y.-X.; Zhang, Z.-J.; Du, B.-Y.; Zhang, X.-H.*; Fan, Z.-Q. Sonochemical Transformation of Epoxy–Amine Thermoset into Soluble and Reusable Polymers. Macromolecules 2015, 48, 316-322.

　　(7) Luo, M.; Zhang, X.-H.*; Darensbourg, D. J. An Investigation of the Pathways for Oxygen/Sulfur Scramblings during the Copolymerization of Carbon Disulfide and Oxetane. Macromolecules 2015, 48, 5526-5532.

　　(8) Luo, M.; Zhang, X.-H.*; Darensbourg, D. J. An Examination of the Steric and Electronic Effects in the Copolymerization of Carbonyl Sulfide and Styrene Oxide. Macromolecules 2015, 48, 6057-6062.

　　(9) Luo, M.; Zhang, X. H.*; Darensbourg, D. J. Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether. Polymer Chemistry 2015, 6, 6955-6958.

　　(10)Luo, M.; Zhang, X. H.*; Darensbourg, D. J. Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides. Catalysis Science & Technology 2015. Advance Article. DOI: 10.1039/C5CY00977D

　　2014

　　(1) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Alternating copolymerization of carbonyl sulfide and Cyclohexene Oxide catalyzed by zinc–cobalt double metal cyanide complex. Polymer 2014, 55, 3688-3695.

　　(2) Wei, R.-J.; Zhang, X.-H.*; Zhang, Y.-Y.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Functional poly (carbonate-co-ether) synthesis from glycidyl methacrylate/CO2 copolymerization catalyzed by Zn–Co (III) double metal cyanide complex catalyst. RSC Advances 2014, 4, 3188-3194.

　　(3) Wei, R.-J.; Zhang, Y.-Y.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Regio-selective synthesis of polyepichlorohydrin diol using Zn–Co (III) double metal cyanide complex. RSC Advances 2014, 4, 21765-21771.

　　(4) Zhang, Y.-Y.; Zhang, X.-H.*; Wei, R.-J.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Synthesis of fully alternating polycarbonate with low T g from carbon dioxide and bio-based fatty acid. RSC Advances 2014, 4, 36183-36188.

　　(5) Zhang, X.-H.*; Min, Y.-Q.; Hua, Z.-J. Epoxy-Based Electronic Materials Containing Nitrogen Heterocyclic Ring: Flame Retardancy. Progress in chemistry 2014, 26, 1021-1031.

　　(6) Hong, J.-L.; Zhang, X.-H.*; Wei, R.-J.; Wang, Q.; Fan, Z.- Q.; Qi, G.-R. Inhibitory effect of hydrogen bonding on thermal decomposition of the nanocrystalline cellulose/poly (propylene carbonate) nanocomposite. Journal of Applied Polymer Science 2014, 131.

　　(7) Zhou, X.-J.; Zhou, Y.-Y.; Nie, J.-J.; Xu, J.-T.; Zhang, X.-H.; Du, B.-Y.* Thermosensitive Ionic Microgels

　　via Surfactant-Free Emulsion Copolymerization and in Situ Quaternization Cross-Linking. ACS Applied Materials & Interfaces 2014, 6, 4498-4513.

　　(8) Chen, T.-Q.; Lu, Y.-P.; Chen, T.-Y.; Zhang, X.-H.; Du, B.-Y.* Adsorption of PNIPAm x-PEO 20-PPO 70-PEO 20-PNIPAm x pentablock terpolymer on gold surfaces: effects of concentration, temperature, block length, and surface properties. Physical Chemistry Chemical Physics 2014, 16, 5536-5544.

　　2013

　　(1) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Sun, X.-K.; Fan, Z.-Q.; Qi, G.-R. Highly Regioselective and Alternating Copolymerization of Racemic Styrene Oxide and Carbon Dioxide via Heterogeneous Double Metal Cyanide Complex Catalyst. Macromolecules 2013, 46, 3693-3697.

　　(2) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Regioselective and Alternating Copolymerization of Carbonyl Sulfide with Racemic Propylene Oxide. Macromolecules 2013, 46, 5899-5904.

　　(3) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Selective production of poly (carbonate–co–ether) over cyclic carbonate for epichlorohydrin and CO2 copolymerization via heterogeneous catalysis of Zn–Co (III) double metal cyanide complex. Polymer 2013, 54, 6357-6362.

　　(4) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Synthesis of bis (cyclic carbonate) and propylene carbonate via a one-pot coupling reaction of CO2, bisepoxide and propylene oxide. RSC Advances 2013, 3, 17307-17313.

　　(5) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Highly Active and Selective Binary Catalyst System for the Coupling Reaction of CO2 and Hydrous Epoxides. Journal of Molecular Catalysis A: Chemical 2013, 379, 38-45.

　　(6) Lu, Y.-P.; Chen, T.-Q.; Mei, A.-X.; Chen, T.-Y.; Ding, Y.-W.; Zhang, X.-H.; Xu, J.-T.; Fan, Z.-Q.; Du, B.-Y.* Solution behaviors and microstructures of PNIPAm-P123-PNIPAm pentablock terpolymers in dilute and concentrated aqueous solutions. Physical Chemistry Chemical Physics 2013, 15, 8276-8286.

　　(7) Chen, T.-Y.; Du, B.-Y.*; Zhang, X.-H.; Fan, Z.-Q. Fabrication of Polymer Nanocapsules with Controllable Oligo (Ethylene Glycol) Densities, Permeation Properties and Robustly Crosslinked Walls. ACS Applied Materials & Interfaces 2013, 5, 3748-3756.

　　2012

　　(1) Sun, X.-K.; Zhang, X.-H.*; Wei, R.-J.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. Mechanistic insight into initiation and chain transfer reaction of CO2/cyclohexene oxide copolymerization catalyzed by zinc-cobalt double metal cyanide complex catalysts. Journal of Polymer Science Part A: Polymer Chemistry 2012, 50, 2924-2934.

　　(2) Sun, X.-K.; Chen, S.; Zhang, X.-H.*; Qi, G.-R. Double Metal Cyanide Complex Catalyst and Its Catalysis for Epoxides-Involved Polymerization. Progress in Chemistry 2012, 24, 1776-1784.

　　(3) Lu, Y.-P.; Zhang, X.-H.; Fan, Z.-Q.; Du, B.-Y.* Adsorption of PNIPAm 110-PEO 100-PPO 65-PEO 100-PNIPAm 110 pentablock terpolymer on hydrophobic gold. Polymer 2012, 53, 3791-3801.

　　2011

　　(1) Zhang, J.-F.; Ren, W.-M.; Sun, X.-K.; Meng, Y.; Du, B.-Y.; Zhang, X.-H.* Fully Degradable and Well-Defined Brush Copolymers from Combination of Living CO2/Epoxide Copolymerization, Thiol–Ene Click Reaction and ROP of ε-caprolactone. Macromolecules 2011, 44, 9882-9886.

　　(2) Zhang, X.-H.*; Wei, R.-J.; Sun, X.-K.; Zhang, J.-F.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Selective copolymerization of carbon dioxide with propylene oxide catalyzed by a nanolamellar double metal cyanide complex catalyst at low polymerization temperatures. Polymer 2011, 52, 5494-5502.

　　(3) Meng, Y.; Zhang, X.-H.*; Du, B.-Y.; Zhou, B.-X.; Zhou, X.; Qi, G.-R. Thermosets with core–shell nanodomain by incorporation of core crosslinked star polymer into epoxy resin. Polymer 2011, 52, 391-399.

　　2010

　　(1) Sun, X.-K.; Zhang, X.-H.*; Chen, S.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. One-pot terpolymerization of CO2, cyclohexene oxide and maleic anhydride using a highly active heterogeneous double metal cyanide complex catalyst. Polymer 2010, 51, 5719-5725.

　　(2) Mei, A.-X.; Guo, X.-L.; Ding, Y.; Zhang, X.-H.; Xu, J.-T.; Fan, Z.-Q.; Du, B.-Y.* PNIPAm-PEO-PPO-PEO-PNIPAm pentablock terpolymer: synthesis and chain behavior in aqueous solution. Macromolecules 2010, 43, 7312-7320.

　　(3) Huang, Y.-J.; Zhang, X.-H.*; Hua, Z.-J.; Qi, G.-R. Calcium chloride doped zinc-cobalt metal-cyanide complex: Unexpected highly activity towards ring-opening polymerization of propylene oxide. Chinese Chemical Letters 2010, 21, 897-901.

　　(4) Huang, Y.-J.; Zhang, X.-H.*; Hua, Z.-J.; Chen, S.-L.; Qi, G.-R. Ring‐Opening Polymerization of Propylene Oxide Catalyzed by a Calcium‐Chloride‐Modified Zinc‐Cobalt Double Metal‐Cyanide Complex. Macromolecular Chemistry and Physics 2010, 211, 1229-1237.

　　2009

　　(1) Zhou, B.-X.; Huang, Y.-J.; Zhang, X.-H.*; Fu, Z.-S.; Qi, G.-R. Thermal properties of an epoxy cresol‐formaldehyde novolac/diaminodiphenyl sulfone system modified by bismaleimide containing tetramethylbiphenyl and aromatic ether structures. Polymer Engineering & Science 2009, 49, 1525-1532.

　　(2) Zhang, X.-H.*; Zhou, B.-X.; Sun, X.-K.; Qi, G.-R. Cure kinetics and thermal properties of tetramethylbiphenyl epoxy resin/phthalazinone‐containing diamine/hexa (phenoxy) cyclotriphophazene system. Journal of Applied Polymer Science 2009, 114, 1397-1404.

　　(3) Huang, Z.-Z.; Zhang, X.-H.*; Qi, G.-R. Novel halogen-free flame retardant thermoset from a hybrid hexakis (methoxymethyl) melamine/phosphorus-containing epoxy resin cured with phenol formaldehyde novolac. Express Polym. Lett 2009, 3, 788-796.

　　(4) Du, B.-Y.*; Cao, Z.; Li, Z.-B.; Mei, A.-X.; Zhang, X.-H.*; Nie, J.-J.; Xu, J.-T.; Fan, Z.-Q. One-Pot preparation of hollow silica spheres by using thermosensitive poly (N-isopropylacrylamide) as a reversible template. Langmuir 2009, 25, 12367-12373.

　　2008

　　(1) Zhang, X.-H.*; Liu, F.; Sun, X.-K.; Chen, S.; Du, B.-Y.; Qi, G.-R.; Wan, K.-M. Atom-exchange coordination polymerization of carbon disulfide and propylene oxide by a highly effective double-metal cyanide complex. Macromolecules 2008, 41, 1587-1590.

　　(2) Zhang, X.-H.*; Zhou, B.-X.; Sun, X.-K.; Qi, G.-R. Preparation and properties of epoxy/phenol formaldehyde novolac/hexakis (methoxymethyl) melamine hybrid resins from in situ polymerization. Journal of Applied Polymer Science 2008, 110, 4084-4092.

　　(3) Sun, X.-K.; Zhang, X.-H.*; Liu, F.; Chen, S.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. Alternating copolymerization of carbon dioxide and cyclohexene oxide catalyzed by silicon dioxide/Zn-Co(III) double metal cyanide complex hybrid catalysts with a nanolamellar structure. Journal of Polymer Science Part A:Polymer Chemistry 2008, 46, 3128-3139.

　　2007

　　(1) Zhang, X.-H.; Hua, Z.-J.; Chen, S.; Liu, F.; Sun, X.-K.; Qi, G.-R.* Role of zinc chloride and complexing agents in highly active double metal cyanide catalysts for ring-opening polymerization of propylene oxide. Applied Catalysis A: General 2007, 325, 91-98.

　　(2) Zhang, X.-H.; Liu, F.; Chen, S.; Qi, G.-R.* Novel flame retardant thermosets from nitrogen‐containing and phosphorus‐containing epoxy resins cured with dicyandiamide. Journal of Applied Polymer Science 2007, 106, 2391-2397.

　　(3) Zhang, X.-H.; Chen, S.; Wu, X.-M.; Sun, X.-K.; Liu, F.; Qi, G.-R.* Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2. Chinese Chemical Letters 2007, 18, 887-890.

　　(4) Zhang, X.-H.*; Huang, L.-H.; Chen, S.; Qi, G.-R. Improvement of thermal properties and flame retardancy of epoxy-amine thermosets by introducing bisphenol containing azomethine moiety. eXPRESS Polymer Letters 2007, 1, 326-332.

　　(5) Zhang, X.-H.; Chen, S.; Chen, T.; Sun, X.-K.; Liu, F.; Qi, G.-R.* Synthesis of a soluble azomethine‐containing bisphenol and the properties of its modified epoxy thermosets. Journal of Applied Polymer Science 2007, 106, 1632-1639.

　　(6) Chen, S.; Zhang, X.-H.; Lin, F.; Qi, G.-R.* Preparation of double metal cyanide compleces from water-insoluble zinc compounds and their catalytic performance for copolymerization of epoxide and CO2. Reaction Kinetics and Catalysis Letters 2007, 91, 69-75.

　　2006

　　(1) Zhang, X.-H.; Chen, S.; Min, Y.-Q.; Qi, G.-R.* Synthesis of novel bisphenol containing phthalazinone and azomethine moieties and thermal properties of cured diamine/bisphenol/DGEBA polymers. Polymer 2006, 47, 1785-1795.

　　(2) Zhang, X.-H.; Min, Y.-Q.; Zhao, H.; Wan, H.-M.; Qi, G.-R.* Novel nitrogen‐containing epoxy resin. II. Cure kinetics by differential scanning calorimetry. Journal of Applied Polymer Science 2006, 100, 3483-3489.

　　著作：

　　1, Yuan Meng, Xinghong Zhang*. Nanostructure Formation in Thermoset/Block Copolymer and Thermoset/Hyperbranched Polymer Blends (pages 161-194, Chapter 6 of book: Nanostructured Polymer Blends, edited by Sabu Thomas, Robert Shanks et al), Elsevier Inc, 2013-12, ISBN(ASIN): 1455731595, 條形碼: 978-1-4557-3159-6, William Andrew publishing(出版社);叢書名: Micro & Nano Technologies

　　2, Yuan Meng, Xinghong Zhang*. Nanostructured epoxy composites (Chapter 3 of book: Micro and Nanostructured Epoxy/Rubber Blends), Wiley-VCH Verlag GmbH, 2014-02. ISBN(ASIN) 3527333347,條形碼：978-3-527-33334-9, Germany.

　　提供技術(shù)

　　聚碳酸酯多元醇合成技術(shù)及其產(chǎn)品;

　　高性能/無鹵阻燃環(huán)氧樹脂;

　　綠色增塑劑;

　　3D打印線材和光固化油墨技術(shù)及產(chǎn)品。

　　獲得榮譽(yù)

　　1、發(fā)表在Polymer上的論文《Selective copolymerization of carbon dioxide with propylene oxide catalyzed by a nanolamellar double metal cyanide complex catalyst at low polymerization temperatures》 (2011, 52(24), 5494-5502)獲得2012年度馮新德最佳論文提名獎(jiǎng)(ELSEVIER出版社)。

　　2、 2014年 《粘接》雜志，《非異氰酸酯路線合成聚羥氨酯的研究》在“中國膠粘劑行業(yè)首屆優(yōu)秀科技論文有獎(jiǎng)?wù)魑拇筚?rdquo;中，獲得“杰出獎(jiǎng)”論文的榮譽(yù)。

　　3、

　　2013年浙江大學(xué)求是青年學(xué)者;

　　2012年浙江省自然科學(xué)學(xué)術(shù)獎(jiǎng)三等獎(jiǎng)，排名1;

　　2012年校級(jí)教學(xué)成果獎(jiǎng)，排名第五;

　　浙江大學(xué)2014年度院級(jí)先進(jìn)工作者.

　　團(tuán)體/社會(huì)/學(xué)術(shù)兼職

　　1. 國家自然科學(xué)基金評(píng)審專家;浙江省自然科學(xué)基金通訊評(píng)議人

　　2. 浙江省粘接技術(shù)協(xié)會(huì)常務(wù)理事(2014-2019);

　　3.《粘接》雜志特約撰稿人(2015-2017)。